You have the emulators installed, but the systems will not show up until you actually copy games/ROMs on it - see https://retropie.org.uk/docs/First-Installation/#emulationstation.
EDIT: when using macOS to transfer ROMs, use the Finder's Go menu and then Connect to Server, type smb://retropie and then hit Connect. See https://retropie.org.uk/docs/Transferring-Roms/#samba-shares.