No, I have not access samba shares via the mac before. I do have file sharing enabled. arp -a returned the following
Kxxxxxx-Mxxxxxx-MacBook-Pro:~ kxxxxxxxxxxxxx$ arp -a
? (10.xxx.x.x) at f4:3e:9d:3:65:15 on en1 ifscope [ethernet]
? (10.xxx.xxx.xxx) at ff:ff:ff:ff:ff:ff on en1 ifscope [ethernet]
Kxxxxxx-Mxxxxxx-MacBook-Pro:~ kxxxxxxxxxxxxx$
it does not find the Pi