@thellin1
You could create an m3u index to point to the iso files or even cue, bin or pbp files.
Legend of Dragoon (Disc 1).m3u contents:
./Legend of Dragoon (Disc 1).iso
./Legend of Dragoon (Disc 2).iso
./Legend of Dragoon (Disc 3).iso
./Legend of Dragoon (Disc 4).iso
This way there is no need to append the image, because the index is already there.
If you wanted to go the extra effort, you could create a folder for the game, and then make an m3u index for each disc. that way you will be able start on disc3 if the first entry in the index is disc3.
Legend of Dragoon (Disc 3).m3u
./Legend of Dragoon (Disc 3).iso
./Legend of Dragoon (Disc 1).iso
./Legend of Dragoon (Disc 2).iso
./Legend of Dragoon (Disc 4).iso
Though additionally you would have to symlink all the memorycards to the same one.
make sure there is only the 1 memory card you want to keep and link to: "Legend of Dragoon.srm" and delete the others or else the links wont be made.
ln -s "Legend of Dragoon.srm" "Legend of Dragoon (Disc 1).srm" "Legend of Dragoon (Disc 2).srm" "Legend of Dragoon (Disc 3).srm" "Legend of Dragoon (Disc 4).srm"
provided those are the names for the m3u indices.
You could also use a program called PSX2PSP to convert and compress all of the discs into a single or individual PBP file that can be loaded in EmulationStation.