Sure, but it's quite a stretch to ask a specific Windows question on a forum dedicated to a Linux retro-gaming solution. You're not using RetroPie, just Emulationstation - and your question has nothing to do with it.
Do you have any helpful input?
You should ask on a specific Windows gaming forum, not here. Since I also use Windows - but not for gaming -, I could tell you what you're trying to do is not possible, but that would also be a stretch, because I don't have your setup.