The .bin file is not editable in a text editor, the .cue is. Looks like the .cue is valid, check if the filename of the .bin is _exactly Final Fantasy VII [NTSC-U] [Disc1of3] [SCUS-94163].BIN.
Remember that Linux is case sensitive so
Final Fantasy VII [NTSC-U] [Disc1of3] [SCUS-94163].bin is not the same as Final Fantasy VII [NTSC-U] [Disc1of3] [SCUS-94163].BIN.
If it's not a name mismatch, then try posting the whole log file (with verbose logging turned on) on pastebin.com to take a look.