I was under the impression that tweakvc would work for RaspiOS Buster based systems, despite the comment on the project page.
Other option would be to add a correct sdtv_mode to config.txt - see here - but that would enable it permanently and wouldn't be a toggle as it is with tweakvc.
EDIT: it seems that the official firmware doesn't have PAL60 support, only some experimental versions which were beta tested as part of the Github topic mentioned above.